Organometallics 32:4571–4576, Saha B, Sengupta G, Sarbajna A, Dutta I, Bera JK (2014) Amide synthesis from alcohols and amines catalyzed by a RuII–N-heterocyclic carbene (NHC)–carbonyl complex. How sodide ion stabilized in solution ? ACS Catal. Dutta I, Sarbajna A, Pandey P, Rahaman SM, Singh K, Bera JK. Pandey, P., Dutta, I. 2002;418:964–7. 1988;1154−6. Green Chem. J Chem Soc Chem Commun 248–249. Nielsen M. Hydrogen production by homogeneous catalysis: alcohol acceptorless dehydrogenation. Baratta W, Chelucci G, Gladiali S, Siega K, Toniutti M, Zanette M, et al. DFT study of acceptorless alcohol dehydrogenation mediated by ruthenium pincer complexes: ligand tautomerization governing metal ligand cooperation. Selective catalytic oxidation of sugar alcohols to lactic acid. Everyday life chemistry We can not move for a moment without help of chemistry. J Chem Soc Dalton Trans 489–495. 2017;7:4462–6. 1985;282:C7–10. Angew Chem Int Ed 50:9593–9597, Shahane S, Fischmeister C, Bruneau C (2012) Acceptorless ruthenium catalyzed dehydrogenation of alcohols to ketones and esters. 1981;11:365–70. Nat Chem 3:216–222, Salvatore RN, Yoon CH, Jung KW (2001) Synthesis of secondary amines. (c) Luo Z, Qin F, Yan S, Li X. VSEPR theory-definition-postulates-shape and limitations, Werner’s co-ordination theory-primary valency-secondary valency. Why alkyl iodides are purple in the presence of sunlight and Role of solvents in SN1 and SN2 reaction ? © 2020 Springer Nature Switzerland AG. Angew Chem Int Ed. Nature. 2012;51:12790−4. See for example: (a) Van der Sluys LS, Kubas GJ, Caulton KG. Well-defined iron catalysts for the acceptorless reversible dehydrogenation- hydrogenation of alcohols and ketones. Chem Commun 655–656. Why quinuclidine is a stronger base than aniline and N, Why the nucleophilic substitution reaction of 1-chloro-2, Xenon fluorides-xenon fluorides act as a strong oxidizing agent, [FeF6]3– ion paramagnetic while [Fe(CN)6]4–ion diamagnetic, [Ni(NH3)6]2+paramagnetic while [Ni (CN) 6]4-diamagnetic, activating groups-explanation-list with application. 2016;138:4298−301. Aspirin-use of aspirin and aspirin from phenol . Google Scholar, West JG, Huang D, Sorensen EJ (2015) Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis. J Am Chem Soc. J Organomet Chem 771:124–130, Prokopchuk DE, Morris RH (2012) Inner-sphere activation, outer-sphere catalysis: theoretical study on the mechanism of transfer hydrogenation of ketones using iron(II) PNNP eneamido complexes. (a) Casey CP, Singer S, Powell DR, Hayashi RK, Kavana M. Hydrogen transfer to carbonyls and imines from a hydroxycyclopentadienyl ruthenium hydride: evidence for concerted hydride and proton transfer. 2016;340:331–43. 2011;15:1052−62. What is chemical bonding and What is dative bond ? Magnetic properties of transition metals. (a) Yamamoto N, Obora Y, Ishii Y. Iridium-Catalyzed oxidative methyl esterification of primary alcohols and diols with methanol. of alcohol reactions, dehydrogenation of alcohol, dehydrogenation of alcohol Organometallics. Angew Chem Int Ed 44:6318–6323, Rodríguez-Lugo RE, Trincado M, Vogt M, Tewes F, Santiso-Quinones G, Grützmacher H (2013) A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures. 1977;16:137–42. What is electro cyclic reaction and symmetry forbidden-symmetry allowed process ? Concerted transfer of OH and CH hydrogens from an alcohol to a (cyclopentadienone)ruthenium complex. Rapid thermal hydrogen production from alcohols catalyzed by [Rh(2,2′-bipyridyl) 2]Cl. 2016;6:381–8. Compounds Angew Chem Int Ed 47:1814–1818, Himo F, Eriksson LA, Maseras F, Siegbahn PEM (2000) Catalytic mechanism of galactose oxidase: a theoretical study. Chem Eur J 20:6542–6551, Patra SK, Bera JK (2007) C–C bond forming reaction through aldol-type addition mediated by a [Ru2(CO)4]2+ core. 2009:753−62. Crotti C, Kasparb J, Farnetti E. Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P–N ligands. the secondary alcohol is oxidized. Dehydrogenation of 2-butanol over the same catalyst was observed m the tem- perature range 248-332C. Science. Dalton Trans 753–762, Hamid MHSA, Slatford PA, Williams JMJ (2007) Borrowing hydrogen in the activation of alcohols. 2014;7:2419–22. 2015;54:9057−60. Computational mechanistic studies of acceptorless dehydrogenation reactions catalyzed by transition metal complexes. Get instant unlimited access to the article. J Organomet Chem. Science. thanks Department of Atomic Energy for DAE outstanding investigator award. J Am Chem Soc. acceptorless catalytic dehydrogenation of 1-phenylethanol. Hydrogen-transfer catalysis with Cp*IrIII complexes: the influence of the ancillary ligands. catalyst at a temperature of 300 ᵒC, the alcohol is oxidized to produce J Am Chem Soc 131:8410–8412, Fujita KI, Yoshida T, Imori Y, Yamaguchi R (2011) Dehydrogenative oxidation of primary and secondary alcohols catalyzed by a Cp*Ir complex having a functional C, N-chelate ligand. Methanol dehydrogenation by iridium N‑Heterocyclic carbene complexes. Chem Eur J 16:6820–6827, Makarov IS, Fristrup P, Madsen R (2012) Mechanistic Investigation of the ruthenium–N-heterocyclic carbene catalyzed amidation of amines with alcohols. (c) Frederick MO, Frank SA, Vicenzi JT, LeTourneau ME, Berglund KD, Edward AW, et al. 2011;50:3533–7. J Am Chem Soc. Catal Sci Technol 2:1425–1428, Bonitatibus PJ Jr, Chakrabortyb S, Dohertya MD, Siclovana O, Jones WD, Soloveichika GL (2015) Reversible catalytic dehydrogenation of alcohols for energy storage. How do you explained the bonding of the carbonyl groups in the structure of Fe2(CO)9 through IR-spectra ? shielding effect Slater's rules and its limitations. 2011;13:1960–79. Acc Chem Res 42:1117–1127, Gray TG, Veige AS, Nocera DG (2004) Cooperative bimetallic reactivity: hydrogen activation in two-electron mixed-valence compounds. Decarbonylation of ethanol to methane, carbon monoxide and hydrogen by a [PNP]Ir complex. Organometallic 28:6578–6584, Musa S, Shaposhnikov I, Cohen S, Gelman D (2011) Ligand–metal cooperation in PCP pincer complexes: rational design and catalytic activity in acceptorless dehydrogenation of alcohols. 2006;25:3007−11. Org Lett 15:650–653, Ghatak T, Sarkar M, Dinda S, Dutta I, Rahaman SMW, Bera JK (2012) Olefin oxygenation by water on an iridium center. Why furan 2-aldehyde undergoes cannizaro reaction but pyrrole 2-aldehyde does not-explain ? Chem Commun 466–468. Angew Chem Int Ed 41:2008–2022, Noyori R, Sandoval CA, Muňiz K, Ohkuma T (2005) Metal–ligand bifunctional catalysis for asymmetric hydrogenation. Double salts-definition-examples and properties in co-ordination chemistry . 2011;76:2937–41. 2010;39:81−8. produced cannot be re-oxidized and converted into carboxylic acids. Lu Z, Demianets I, Hamze R, Terrile NJ, Williams TJ. Catalytic hydrogenation of esters. Which have more π-acceptor strength among the CO. Nat Commun 6:10093, ADS  hydrogen from organic molecules. ACS Catal. Chemistry is the very important part of our daily life .... What is dehydrogenation of alcohol reactions in organic chemistry? Available at: Raney Ni-Sn catalyst for H2 production from biomass-derived hydrocarbons. Org Process Res Dev. Huber GW, Dumesic JA. 2014;7:2464−503. 2007:522–4. Hydride transfer reactions catalyzed metal complexes. Raney Ni-Sn catalyst for H. production from biomass-derived hydrocarbons. Jung CW, Garrou PE. Stereoselective decarbonylation of methanol to form a stable Iridium(III) trans-Dihydride Complex. Organometallics 26:2598–2603, Stevens CV, Vekemans W, Moonen K, Rammeloo T (2003) Synthesis of 4-phosphono-β-lactams via phosphite addition to acyliminium salts. (a) Fujita K, Kawahara R, Aikawa T, Yamaguchi R. Hydrogen production from a methanol−water solution catalyzed by an anionic iridium complex bearing a functional bipyridonate ligand under weakly basic conditions. Chem Commun. Efficient selective and atom economic catalytic conversion of glycerol to lactic acid. J Am Chem Soc. Chem Commun 90–91. 1977;16:137–42. Magnetic properties of transition metals. formal charge calculation and significance . Angew Chem Int Ed 50:3533–3537, Azerraf C, Shpruhman A, Gelman D (2009) Diels–Alder cycloaddition as a new approach toward stable PC(sp3)P-metalated compounds. Dusselier M, van Wouwe P, Dewaele A, Makshina E, Sels BF. Chem Rev. 2006;45:3982. (g) Melnick JG, Radosevich AT, Villagran D, Nocera DG. Proc. 2015;6:6859. Data from Renewal Fuels Association (RFA). Sponholz P, Mellmann D, Cordes C, Alsabeh PG, Li B, Li Y, et al. Top Organomet Chem 37:55–84, Cundari RT, Klinckman TR, Wolczanski PT (2002) Carbon–hydrogen bond activation by titanium imido complexes. Zonetti PC, Celnik J, Letichevsky S, Gaspar AB, Appel LG. J Am Chem Soc 127:10840–10841, Spasyuk D, Gusev DG (2012) Acceptorless dehydrogenative coupling of ethanol and hydrogenation of esters and imines. Why methyl chloride (CH3Cl) is inactive in SN1 reaction and (CH3)3C-Cl ( t-butyl chloride) is inactive in SN2 reaction ? Accessed: 10 Aug 2017. 2014;6:3018–26. 2013;52:6326−9. 2011;50:9593−7. Conley BL, Pennington-Boggio MK, Boz E, Williams TJ. ortho and para directing and Why ‘Cl’-atom can not form H-bond but ‘N’-atom can ? Dehydrogenation Green Chem. 2010;110:2294–312. Chem Rev. 2013;32:1000–15. Org Lett. (a) Soldevila-Barreda JJ, Romero-Canelon I, Habtemariam A, Sadler PJ. J Mol Catal. 2007;26:4135. Reactivity of (dihydrogen)dihydridotris(triphenylphosphine)ruthenium. J Chem Soc. Therefore the aldehydes and ketones 2008;99:6528–37. 2007;317:790−2. doi:10.1039/B312162C, Johnson TC, Morris DJ, Wills M (2010) Hydrogen generation from formic acid and alcohols using homogeneous catalysts. ). Chem Rev. 2012;23:333–8. On the origin of hydrogen in metal hydride complexes formed by reaction with alcohols. Catalytic production of hydrogen from glucose and other carbohydrates under exceptionally mild reaction conditions. Organometallics. thank CSIR, India for fellowships. J Am Chem Soc 135:967–970, Khusnutdinova JR, Milstein D (2015) Metal–ligand cooperation. Plots of fractional con- version vs reciprocal … J Chem Soc Chem Commun 1154–1156. Chem Eur J 11:7146–7153, van der Vlugt JI (2012) Cooperative catalysis with first-row late transition metals. (b) Nandakumar A, Midya SP, Landge VG, Balaraman E. Transition-metal-catalyzed hydrogen- transfer annulations: access to heterocyclic scaffolds. 2017;9:1113–8. Annu Rev Microbiol. Synthesis, structure, and catalytic dehydrogenation of alcohols and hydrogenation of esters. J Am Chem Soc 131:10354–10355, Grotjahn DB (2005) Bifunctional organometallic catalysts involving proton transfer or hydrogen bonding. (c) Chamoun R, Demirci UB, Miele P. Cyclic dehydrogenation−(re)hydrogenation with hydrogen-storage materials. Google Scholar, Janowicz AH, Bergman RG (1982) C-H activation in completely saturated hydrocarbons: direct observation of M + R–H → M(R)(H). of alcohol reactions, dehydrogenation of alcohol, dehydrogenation of alcohol Dehydrogenation A review of catalytic aqueous-phase reforming of oxygenated hydrocarbons derived from biorefinery water fractions. Acc Chem Res 21:333–340, Lipscomb WN, Sträter N (1996) Recent advances in zinc enzymology. Correspondence to 2003;68:7681. 2016;138:5781–4. 2015;137:3743–6. Dehydrogenation of alcohol reactions examples. 2006;31:5161–3. Compounds 2010;12:1295–300. 2012;51:5711–3. Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide. doi:10.1039/C39830000788, Maguire JA, Boese WT, Goldman AS (1989) Photochemical dehydrogenation of alkanes catalyzed by trans-carbonylchlorobis(trimethylphosphine)rhodium: aspects of selectivity and mechanism. Chem Eur J 21:9833–9849, Casey CP, Johnson JF (2003) Kinetic isotope effect evidence for a concerted hydrogen transfer mechanism in transfer hydrogenations catalyzed by [p-(Me2CH)C6H4Me]Ru-(NHCHPhCHPhNSO2C6H4-p-CH3). 2006;111:119–32. 2015;54:12236–73. Inorg Chem. Coord Chem Rev 249:911–918, Shvo Y, Czarkie D, Rahamim Y, Chodosh DF (1986) A new group of ruthenium complexes: structure and catalysis. Computational evidence for the role of alkane adducts in selective C–H activation. Why pyridine does not exhibits resonance and Why is phenol more acidic than cyclo hexanol ?


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