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- Coupling Reactions. 2 Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents.

Emma L. McInturff, Jeffrey Mowat, Andrew R. Waldeck, and Michael J. Krische . Xiaoyan Wu, Junjie Fan, Chunling Fu, Shengming Ma. Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes. the Altmetric Attention Score and how the score is calculated.

Shutao Qi, Shiquan Gao, Xiaoxiao Xie, Junfeng Yang. Jean E. Glover, David J. Martin, Paul G. Plieger, Gareth J. Rowlands. Kana Tanaka, Tomohiro Ueda, Tomonori Ichibakase, Makoto Nakajima.

Recent developments in asymmetric alkynylations.

Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis. Alkynylation of Aldehydes and Ketones Using the Bu Carbonyl compounds are given as products. Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes. Xiao Wang, Qi Gao, Alexei V. Buevich, Nobuyoshi Yasuda, Yonglian Zhang, Rong-Sheng Yang, Li-Kang Zhang, Gary E. Martin. This reaction allows for the formation of propargylic alcohols under mild conditions, tolerating many functional groups (such as carboxylic acids) that are incompatible with other methods. give aldehydes. The other is the “chiral amine” strategy, applying terminal alkynes, aldehydes, and chiral amines such as (S)- or (R)-α,α-diphenylprolinol or (S)- or (R)-α,α-dimethylprolinol. Catalytic Asymmetric Conjugate Protosilylation and Protoborylation of 2-Trifluoromethyl Enynes for Synthesis of Functionalized Allenes. Ketones cannot be prepared by this reaction.

Takuya Hashimoto, Kazuhiro Fukumoto, Naoyuki Abe, Kazuki Sakata, Keiji Maruoka. M�^�X��6���F��zƌ+r���C�`�{�Y0A, C�.

Garner’s aldehyde as a versatile intermediate in the synthesis of enantiopure natural products. The other is the “chiral amine” strategy, applying terminal alkynes, aldehydes, and chiral amines such as (S)- or (R)-α,α-diphenylprolinol or (S)- or (R)-α,α-dimethylprolinol. Hydration of Aldehydes and Ketones. You have to login with your ACS ID befor you can login with your Mendeley account.

Synthesis, Characterization, and Reactivity of Arene-Stabilized Rhodium Complexes. Enantiocontrolled Synthesis of Tertiary α-Hydroxy-α-ynyl Esters by Dimethylzinc-Mediated Addition of Alkynes to α-Keto Esters. -butylphosphino)biphenyl.

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